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– Consider the base dissociation-constant expression for ammonia and the acid dissociation constant expression for its conjugate acid, ammonium ion:

Compare the values of the base dissociation constant for ammonia and methylamine: K b (ammonia) = 1.8 × 10 -5 (smaller) K b (methanamine) = 4.4 × 10 -4 (larger) At 25°C, using。

The Kb is the equilibrium constant for the reaction of the base ammonia combining with water to produce ammonium, the conjugate acid, and a hydroxide anion (OH-).

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